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Optical methods provide a continuous flow of hyperpolarized molecules.

The method presented here is fundamentally different.

H nuclei are effectively detected in a 3-Tesla clinical MRI system.

Thus, a vast array of new applications lays dormant, awaiting improved sensitivity.

We demonstrate the potential of this method by NMR and MRI at very low field, and believe that this fundamentally new approach will trigger and catalyse the development of new application in the fields of NMR, MRI and beyond.

The presented method works by continuously producing a hyperpolarized sample of small molecules in solution by means of a chemical exchange reaction with parahydrogen at a low magnetic field of ≈5 m T.

Alternatively, such a catalyst might be targeted, for example, to cancer cells if specificity is required. Further, as one catalyst molecule hyperpolarizes many target molecules, multiple times, the loading need not be high.

Indeed, signal may be acquired until the required signal-to-noise or resolution is achieved.

In fact, it is protected as a singlet, and consequently the lifetime of p H extends to weeks. The hardware requirements for this method however are minimal, as it is based on signal amplification by reversible exchange (SABRE), which was reported in 2009 (ref.8) and has stimulated much discussion in the literature.The presented method works by continuously producing a hyperpolarized sample of small molecules in solution at a low magnetic field of ≈5 m T.The magnetization does not decay and is reinstated after signal detection.




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